Composition and origin of the volatile components released from the Pesyanoe aubrite by stepwise crushing and heating     

《Chemie der Erde / Geochemistry》2021,81(1):125686

Aubrites are achondritic meteorites (enstatite pyroxenites) that were formed in highly reduced magmatic environments on a differentiated parent body sharing a common oxygen isotope reservoir with enstatite chondrites (EC), Earth and Moon, and could be considered as a geochemical model of the early proto-Earth. Some pyroxenes of the Pesyanoe aubrite have high abundance of gaseous inclusions, captured during the crystallization of the rocks. Investigation of the inclusions by IR spectroscopy reveals presence of OH⁻ groups and C–H bonds. The former are assigned to protonated point defects in enstatite lattice and the latter to compounds occupying void walls. Molecular water and CO₂ were not observed. Volatile components released from the samples of the Pesyanoe enstatite by stepwise crushing and heating are composed of CO₂, H₂O and a non-condensable phase. Hydrogen isotopic composition of volatiles extracted in form of molecular water in Px-separates varies in the range δD = −61 – −84‰ with mean value of δD = −73 ± 16‰ VSMOW and is within the ranges of ECs and Earth’s mantle. The total abundance of H₂ in the pyroxene of Pesyanoe were estimated as at least 0.047 ppm that is too low in comparison with that of enstatite chondrites (≥30 ppm H₂) and could indicate nearly complete degassing of the Pesyanoe primitive precursor material during the Pesyanoe parent body accretion or a mantle degassing in igneous differentiation process. In a last case a primitive precursor could have D/H ratio different from that of enstatite chondrites.  相似文献   

Contrasting water–rock interaction behaviors of antimony and arsenic in contaminated rivers around an antimony mine,Hunan Province,China     

《Chemie der Erde / Geochemistry》2021,81(2):125748

Although antimony (Sb) and arsenic (As) exhibit similar geochemical behavior and toxicity in the environment, growing evidence suggests that their water–rock interaction behavior in contaminated rivers is quite different. Twenty-nine river water samples were collected between September and November 2018 from contaminated rivers around an antimony mine in Hunan Province, China. The concentrations of As and Sb were inversely proportional to the water flow distance. The rates and magnitudes of Sb decrease were more prominent than those of As. Silicate mineral dissolution from rocks such as silicified limestone increased the As and Sb concentration of in-mine-district (IMD) water. Dissolution of carbonate minerals, ion exchange, and competitive adsorption were the major water–rock interactions, resulting in rapidly decreasing As and Sb concentration in IMD direct impacted water and IMD indirect impacted water. The behaviors of As and Sb during water–rock interaction were dissimilar for areas dominated by carbonate and silicate minerals.  相似文献   

Groundwater characteristics and climate and ecological evolution in the Badain Jaran Desert in the southwest Mongolian Plateau     

《China Geology》2021,4(3):421-432

The Badain Jaran Desert is the third largest desert in China, covering an area of 50000 km². It lies in Northwest China, where the arid and rainless natural environment has a great impact on the climate, environment, and human living conditions. Based on the results of 1∶250000 regional hydrogeological surveys and previous researches, this study systematically investigates the circulation characteristics and resource properties of the groundwater as well as the evolution of the climate and ecological environment since the Quaternary in the Badain Jaran Desert by means of geophysical exploration, hydrogeological drilling, hydrogeochemistry, and isotopic tracing. The results are as follows. (1) The groundwater in the Badain Jaran Desert is mainly recharged through the infiltration of local precipitation and has poor renewability. The groundwater recharge in the desert was calculated to be 1.8684×10⁸ m³/a using the water balance method. (2) The Badain Jaran Desert has experienced four humid stages since the Quaternary, namely MIS 13-15, MIS 5, MIS 3, and the Early–Middle Holocene, but the climate in the desert has shown a trend towards aridity overall. The average annual temperature in the Badain Jaran Desert has significantly increased in the past 50 years. In detail, it has increased by about 2.5°C, with a higher rate in the south than in the north. Meanwhile, the precipitation amount has shown high spatial variability and the climate has shown a warming-drying trend in the past 50 years. (3) The lakes in the hinterland of the Badain Jaran Desert continuously shrank during 1973–2015. However, the vegetation communities maintained a highly natural distribution during 2000–2016, with the vegetation cover has increased overall. Accordingly, the Badain Jaran Desert did not show any notable expansion in that period. This study deepens the understanding of groundwater circulation and the climate and ecological evolution in the Badain Jaran Desert. It will provide a scientific basis for the rational exploitation of the groundwater resources and the ecological protection and restoration in the Badain Jaran Desert.© 2021 China Geology Editorial Office.  相似文献   

Microplastic pollution in surface water and sediments of Qinghai-Tibet Plateau: Current status and causes     

《China Geology》2021,4(1):178-184

To study the current status and causes of the microplastic pollution in surface water of the Qinghai-Tibet Plateau, this paper compared the average microplastic abundance in sediments and surface water of the Qinghai-Tibet Plateau and the results are as follows. First, the average microplastic abundance in surface water of the independent rivers and the whole area is 247–2686 items/m³ and 856 items/m³, respectively. The average microplastic abundance in sediments of independent rivers or lakes and the whole area is 0–933 items/m² and 362 items/m², respectively. Meanwhile, the degree of microplastic pollution in river sediments is higher than that in lake sediments, and the rivers suffering from microplastic pollution mainly include the Brahmaputra River, Tongtian River, and Nujiang River. Second, compared with the microplastic pollution in other areas of the world, the levelof microplastic pollution in the lakes and rivers of the Qinghai-Tibet plateau is not lower than that of well-developed areas with more intensive human activities. Finally, this study suggests that relevant government departments of the Qinghai-Tibet Plateau should strengthen waste management strategies while developing tourism and that much attention should be paid to the impacts of microplastics in the water environment.©2021 China Geology Editorial Office.  相似文献   

台风“摩羯”与“温比亚”环流中龙卷小尺度涡旋特征及可预警性分析          下载免费PDF全文

刁秀广  孟宪贵  张立  任钟冬  赵海军 《山东气象》2019,39(3):19-28

利用多普勒天气雷达探测资料,结合常规气象观测资料和天气实况及灾情调查,对2018年8月14日台风“摩羯”（1814）和8月19日台风“温比亚”（1818）产生龙卷的环境物理量及龙卷风暴强度结构特征进行了分析,对诱发龙卷和未诱发龙卷的小尺度气旋性涡旋特征进行了对比。结果表明：两次台风减弱低压东北象限是龙卷发生的关键区,低层高湿,强的低层垂直风切变和大的相对风暴螺旋度是关键物理量;龙卷出现时都伴有ΔV＞20.0 m·s-1的小尺度气旋性涡旋,且基本出现在2.0 km高度以下,但并不是所有这种低层小尺度气旋性涡旋都能诱发龙卷;以ΔV＞20.0 m·s-1为阈值,龙卷识别具有较高的命中率,识别准确率为31.8%,空报率为67.4%,漏报率为6.7%;约35.7%的龙卷没有识别时间提前量,半数龙卷几乎没有预警时间提前量。  相似文献   

Polar WRF模式海冰密集度方案对北极海雾模拟效果的个例研究          下载免费PDF全文

宋姝彤  衣立  张苏平  王晓宇  刘一林  陈显尧 《山东气象》2019,39(2):34-42

全球变暖的背景下,北极航线的常规通航甚至商业运营有望实现,而海雾会严重影响航道上船只的航行安全。海冰的存在使海气之间相互作用变得更为复杂,是研究北极海雾不可忽略的因素。船载观测发现,与中纬度常见平流冷却雾形成时气温下降速度往往超过海水降温速度不同,北极海雾发生时海冰的存在还会使海水降温速度超过空气降温速度。然而目前海冰分布是否会影响模式模拟海雾的准确性还不得而知,因此本文利用Polar WRF（Polar Weather Research and Forecasting）模式模拟了中国第七次北极考察中观测到的一次海雾过程,并进行海冰密集度敏感性试验。通过与船载观测和欧洲中期天气预报中心再分析数据比对发现,在低浮冰区内（海冰密集度小于50%）考虑海冰分布时可以更加准确地刻画潜热通量与水汽通量,模拟出与观测事实相符的表层空气降温与增湿过程以及相对湿度的变化,因此能够更好地刻画海雾的三维结构及其生消演变。  相似文献   

三江源区大气可降水量时空特征及其与降水关系     

强安丰  汪妮  解建仓  姜仁贵 《干旱气象》2019,37(1):22-30

利用1979—2016年欧洲中期天气预报中心(ECMWF) ERA-Interim (1°×1°)再分析资料中的经、纬向水汽通量和大气可降水量(precipitation water vapor,PWV)数据,采用相关性分析、趋势分析法、累积距平、IDW等方法,分析三江源地区PWV与水汽通量的时空分布特征、降水转化率(precipitati-on conversion efficiency,PCE)变化规律。结果表明:过去的38 a,经、纬向多年平均水汽通量分别为50. 2、196. 7 kg·m-1·s^(-1),纬向水汽通量气候倾向率比经向大。南边界为纬向主要水汽输入边界,东边界为经向主要水汽输出边界,纬向水汽输送大于经向输送。多年平均PWV为1998. 3 mm,近38 aPWV呈现微弱增加趋势,1979—1997年,PWV呈下降趋势,1998年后PWV呈增加趋势,同期降水也在增加,说明该时段三江源地区气候转湿。PWV与水汽通量的年际变化趋势和转折年相一致。三江源区多年平均PCE为24. 57%,1989年PCE最高,达32. 76%,各季节平均PCE空间分布与年平均PCE分布一致,均表现出南部、东南部高,西部、东北部低的变化特征,各季节PCE大小差异明显,春季多年平均PCE为15. 92%,夏季25. 67%,秋季21. 01%,冬季仅7. 03%。  相似文献   

内蒙古东北部地区一次极端降雪过程的水汽输送特征     

王慧清  付亚男  孟雪峰 《干旱气象》2019,(2):277-287

利用内蒙古呼伦贝尔市常规观测资料和GDAS、NCEP/NCAR再分析资料,采用欧拉方法分析了2016年春季内蒙古东北部地区一次极端暴雪过程的水汽输送及收支特征,利用HYSPLIT模式和聚类分析模拟计算了此次暴雪天气过程的水汽源地、主要水汽输送通道及其对水汽输送的贡献,并与传统的欧拉方法结果进行对比。结果表明:(1)有3支不同源地的水汽流在内蒙古东北部地区交汇,对呼伦贝尔地区暴雪的发生与维持有重要影响;(2)经向和纬向输送为此次暴雪天气的发生提供了充足的水汽,暴雪区水汽主要源于中高层的南边界和随西风气流的西边界;(3)利用HYSPLIT模式模拟发现,在此次暴雪天气过程中水汽主要来源于新地岛以西洋面、日本海以及巴尔喀什湖,且三者贡献率大致相当。  相似文献   

2000年后中国北方东部地区夏季极端降水减少及水汽输送特征   总被引：2，自引：0，他引：2  

李湘瑞  范可  徐志清 《大气科学》2019,43(5):1109-1124

本文研究了1961～2016年中国北方东部地区夏季极端降水日数和极端降水贡献率的年代际变化特征,并进一步分析了该地区极端降水和普通降水的大气环流和水汽输送的差异。主要的研究结果表明:1961～2016年中国北方东部地区夏季极端降水日数和极端降水贡献率在2000年前后发生显著年代际变化,2000年后夏季极端降水天数和极端降水贡献率显著减少。与1984～1999年相比,2000～2016年在对流层高层从欧洲大陆、中亚到东北—蒙古地区,位势高度异常呈现出“正—负—正”的大气波列,从而造成北方东部地区上空为正压的位势高度正异常控制,伴随着下沉运动,大气层结趋于稳定,这些环流条件不利于极端降水发生。2000年后负位相的太平洋年代际振荡（PDO）和正位相的北大西洋多年代际振荡（AMO）共同加强了北方东部地区上空的正位势高度异常。进一步研究表明,极端降水与普通降水的水汽输送和收支以及关键的局地大气系统存在着显著差异,较普通降水而言,极端降水在南北向水汽输送和收支上更强;北方东部地区低空为较强的闭合低压控制,并不断受到高层高位涡空气下传的影响。  相似文献   

闽中南罕见冬季锋前暴雨个例特征分析          下载免费PDF全文

陈健康  赵玉春  陈赛  黄惠镕  郑辉 《气象》2019,45(2):228-239

利用福建省逐小时加密自动站资料、风廓线、S波段双偏振雷达与雨滴谱等新型探测资料以及NCEP逐6 h的1°×1°大气再分析资料,分析了2017年2月21—22日福建中南部一次预报失败的冬季暴雨过程。结果表明:(1)此次暴雨过程类似于锋前暖区暴雨,自2000年以来仅此一例,十分罕见,是在低空急流偏强并长时间维持的背景下产生的,并未受到南支槽和冷空气的影响。(2)闽中大到暴雨带和闽南暴雨区的对流系统相互独立,有多个对流系统影响闽中地区,仅两个对流系统影响闽南地区。降水有较明显对流特征,属暖云弱对流降水,容易导致预报员对雨强估计不足。(3)此次冬季暴雨过程的水汽主要来自南海地区,低层水汽条件与汛期暴雨相当,但整层水汽条件较汛期略差;低空急流对暖湿气流的输送使暴雨区趋于不稳定,但对流不稳定度较汛期弱。(4)高空辐散低层辐合的配置为冬季暴雨带来了有利的动力抬升条件,但暴雨区涡旋性不强,无明显正涡度柱。其中,闽中大到暴雨主要与条件性对称不稳定有关,是在湿斜压作用下倾斜上升运动中产生,而闽南暴雨区既存在对流不稳定,也存在条件性对称不稳定。  相似文献